张绪穆著当,1961年10来自月出生,南方科技大学松谁术根师化学系系主任 、武汉大学讲座教授、绿毛宣色催化研究所所长卷元、宾州州立大学教授、罗360百科格斯-新泽西时较武想热且宽许州立大学终身教授,苗吧博士生导师。职称职务:南方科技大学化学系系主任 、武汉大学讲座教授、绿色催化研农村编班艺史究所所长、宾州州立大学教授、罗格斯-新泽西州立大学终身教授林破务银子显,博士生导师。
- 中文名称 张绪穆
- 外文名称 Zhang Xumu
- 国籍 中国
- 民族 汉族
- 出生日期 1961年10月
人物经历
1982年毕业于武汉大学化学系,获学士学位,1992年毕业于斯坦福大学(Stanford)化学系,获博士学位。1992年至1994年在斯坦福大学(Stanford University)化学系做博士后研究。1994年至1999年于宾州州立大学(Penn State University)任助理教授,1999年至2来自003年于宾州州立大下古话坚片质因则执下校学(Penn State University)任副教授,2003年9月至今于宾州州立大学(Penn State University)任教授。已发表文章90多篇,专利及专利申请42件,曾多次被邀请在国际会议上做报告 (正式受邀演讲: 210 次,其他受邀演讲: 75 次)。并且是美国凯瑞生化有限公司(Chiral Quest Inc)的创始人和首席技术总监。
2015年,就任南方科技大学化学系系主任 。
研究方向
研究方向:有机化学、金属有机化学、生物无机化学。
主要贡献
触职声教 近期代表性研究论文:
1.Catalytic Enantioselective Desymmetrization of Meso Cy来自clic Anhydrides via Iridium-Catalyzed Hydrogenati360百科on. Liu, T. L.; Li, W.; Geng, H. L.; Wang, C. J.; Zhang, X. M. Or轴源倍法地装突ganic Letters. 2013, 15, 1740.
2.Rhodium-Catalyzed Asymmetric Hy诉步看坚胡省波没孔毛如droformylation 兴具of 1,1-Disubstituted Allylphthalimides: A Catalytic Route to β3-Amino Acids. Zheng, X.; Cao, B. N.; Liu, T. L.; Zhang, X. M. Advanced Synthesis & Catalysis. 2013, 355, 679.
3.Cascade Synthesis of Fenpiprane and Related Pharmaceuticals via Rhodium-Catalyzed Hydroaminomethylation. Li, S. K.; Huang, K. X.; Zhang, J. W.; Wu, W. J.; Zha血却载底着担扩早独混钢ng, X. M. Organic Letters. 2认重器齐入赶菜击013, 15, 10官于固太处热吸36.
4.A Novel Triphos住phoramidite Ligand for Highl来证鸡妈问编践帮甚跳外y Regioselective Linear Hydroformylation of Terminal and Internal 往翻呼婷乎Olefins Chen, C. Y.; Qiao, Y.; Ge触青依细经鸡础记ng, H. L.; Zhang, X. M. Organic Letters. 2013, 15, 1048.
5.Rhodium-Catalyzed Enantioselective Hydrogenation of Oxime Acetates.Huang, K. X.; Li, S. K.; Chang, M. X.; Zhang, X. M. Organic Letters. 2013, 15, 484.
6.Highly enantioselectiv棉否米e hydrogenation of β,β-disubstituted nitroalkenes. Li, 范多植Shengkun; Huang, Kexuan; Cao, Bonan; Zhang, Jiwen; Wu, Wenjun; Zhang, Xumu. An停道测争序扩仍字示gew. Chem当渐都益养境. Int. Edit. 2012, 51, 10679. DOI: 10.1002/anie.201202715
7.New tetraphosphorus ligands for highly linear selective hydroformylation of allyl and vinyl derivatives. Cai, Chaoxian; Yu, 德刚灯终个练Shichao; Cao, Bonan; Zha仅给界界染ng, Xumu. Che金帮度队渐书样装常m. Eur. J. 2012, 18, DOI: 10.1002/chem.201201396.
8.Access to both enantiomers of α-chloro-β-keto esters with a single chiral ligand: highly efficient enantioselective chlorination of cyclic β-keto esters catalyzed by chiral copper(II) and zinc(II) complexes of a spiro-2,2'-bischroman-based bisoxazoline ligand. Li, Jie; Pan, Wei; Wang, Zheng; Zhang, Xumu; Ding, Kuiling. Adv. Synth. Catal. 2012, 354, 1980.
9.Highly enantioselective hydrogenation of β-ketoenamides with the Rh-ZhangPhos catalyst. Huang, Kexuan; Zhang, Xiaowei; Geng, Huiling; Li, Sheng-kun; Zhang, Xumu. ACS Catalysis 2012, 2, 1343.
10.Highly regioselective isomerization-hydroaminomethylation of internal olefins catalyzed by Rh complex with Tetrabi-type phosphorus ligands. Liu, Guodu; Huang, Kexuan; Cao, Bonan; Chang, Mingxin; Li, Shengkun; Yu, Shichao; Zhou, Le; Wu, Wenjun; Zhang, Xumu. Org. Lett. 2012, 14, 102.
11.Highly regioselective hydroaminomethylation of terminal olefins to linear amines using Rh complexes with a Tetrabi phosphorus ligand. Liu, Guodu; Huang, Kexuan; Cai, Chaoxian; Cao, Bonan; Chang, Mingxin; Wu, Wenjun; Zhang, Xumu. Chem. Eur. J. 2011, 17, 14559.
12.Ruthenium-catalyzed asymmetric hydrogenation of β-keto enamines: an efficient approach to chiral γ-amino alcohols. Geng, Huiling; Zhang, Xiaowei; Chang, Mingxin; Zhou, Le; Wu, Wenjun; Zhang, Xumu. Adv. Synth. Catal. 2011, 353, 3039.
13.Highly regioselective isomerization-hydroformylation of internal olefins catalyzed by Rhodium/tetraphosphine complexes. Cai, Chaoxian; Yu, Shichao; Liu, Guodu; Zhang, Xiaowei; Zhang, Xumu. Adv. Synth. Catal. 2011, 353, 2665.
14.A highly efficient and enantioselective access to tetrahydroisoquinoline alkaloids: asymmetric hydrogenation with an Iridium catalyst. Chang, Mingxin; Li, Wei; Zhang, Xumu. Angew. Chem. Int. Edit. 2011, 50, 10679.
15.Spiro-2,2'-bichroman-based bisoxazoline (SPANbox) ligands for Zn(II)-catalyzed enantioselective hydroxylation of β-keto esters and 1,3-diester. Li, Jie; Chen, Gang; Wang, Zheng; Zhang, Ruzhou; Zhang, Xumu; Ding, Kuiling. Chem. Sci. 2011, 2, 1141.
16.New synthetic strategy for high-enantiopurity N-protected α-amino ketones and their derivatives by asymmetric hydrogenation. Sun, Tian; Hou, Guohua; Ma, Miaofeng; Zhang, Xumu. Adv. Synth. Catal. 2011, 353, 253.
17.Enantioselective synthesis of optically pure β-amino ketones and γ -aryl amines by Rh-catalyzed asymmetric hydrogenation. Geng, Huiling; Huang, Kexuan; Sun, Tian; Li, Wei; Zhang, Xiaowei; Zhou, Le; Wu, Wenjun; Zhang, Xumu. J. Org. Chem. 2011, 76, 332.
18.Synthesis of enamides via Cu(I)-catalyzed reductive acylation of ketoximes with NaHSO3. Guan, Zheng-Hui; Zhang, Zhi-Yuan; Ren, Zhi-Hui; Wang, Yao-Yu; Zhang, Xumu. J. Org. Chem. 2011, 76, 339.
发明专利:
"New Chiral Ferrocene Phosphines and Their Applications for Asymmetric Catalytic Reactions" X. Zhang, US patent 09/781,083, filed February 9, 2001 and PCT/US01/044.
2."3,3'-Substituted Chiral Biaryl Phosphines and Phosphintes for Asymmetric Catalytic Reactions " X. Zhang, U. S. Patent, filed November 16, 2001 and PCT Application.
3."New Transition Metal Catalyzed Reactions" A. Lei, X. Zhang, U. S. Provisional Patent, filed March 30, 2001.
4. "New Chiral Phospholanes for Asymmetric Catalysis" X. Zhang, US Patent filed November 6, 2001.
5. "P-chiral Phospholanes and Phosphocyclic compounds and their use in asymmetric catalytic reactions" W. Tang, X. Zhang, US provisional Patent, November 10, 2001.
6. "Asymmetric Reductive Amination of Ketones" X. Zhang, US Provisional Patent, filed October 25, 2002.
7."P-chiral Phospholanes and Phosphocyclic compounds and their use in asymmetric catalytic reactions" W. Tang, X. Zhang, US Patent, November 10, 2002.
8. "New Chiral Oxazoline Ligands for Asymmetric Catalysis" D. Liu, X. Zhang, US Provisional Patent, December 17, 2003.
9."Asymmetric Hydrogenation of Alpla-amino Carbonyl Compounds" X. Zhang, US Provisional Patent, January 10, 2004
10."Preparation of chiral cyclic amino acids and derivatives" X. Zhang, W. Tang, US Patent 2004242889.
11."P-Chiral Phospholanes and Phosphocyclic Compounds and their use in Asymmetric Catalytic Reactionss" X. Zhang, W. Tang, US patent 2004229846.
12. "Catalytic Asymmetric Reductive Amination of Ketones Via Transition Metal Complex Catalyst with Chiral Phosphine Ligands" X. Zhang, PCT, 2004, WO 2004058982.
13. "Preparation of Chiral Phosphorus Cyclic Compounds for Transition Metal-Catalyzed Asymmetric Reactions" X. Zhang, US patent, 2004, 2004072680.
14. "A preparation of aminoalcohols via asymmetric hydrogenation of beta-aminocarbonyl compounds" Zhang,
15.Xumu. US 2005159604 A1 20050721 Patent written in English. Application: US 2005-36157 20050114.
16."New oxazoline ligands for asymmetric catalysis" Zhang, Xumu; Liu, Duan. U.S. Pat. Appl. Publ. (2005), 2005137403 A1 20050623.
17. "Chelating Tetraphosphorus Ligands with 1,1'-biphenyl backbone for transition Metal-catalyzed hydroformylation of Alkenes and Related Reactions" X. Zhang; Y. Yan, PCT Int. Appl. (2007) 2007078859. A2 20070712.
18.新型三齿膦配体及其在线性氢甲酰化及类似反应中的应用(P). 张绪穆,陈才友. 中国发明专利,CN102875599. 2013-01-16.
获奖记录
Franklin Veatch Graduate Fellowship, 1991, Stanford University
The Camille and Henry Dreyfus Foundation New Faculty Award, 1994
DuPont Young Faculty Award, 1996
Office of Naval Research Young Investigator Award, 1996
The Camille and Henry Dreyfus Foundation Teacher-Scholar Award, 1998
The John Simon Guggenheim Foundation Fellow, 2000
The Outstanding Oversea Chinese Young Scientist B, Chinese Academy of Sciences, 2000
The Penn State Faculty Scholar Medal, 2001
The Young Innovation Award of ChiTec (Chinese High Tech) in Chemistry, 2001
The American Chemical Society Arthur C. Cope Scholar Award, 2002
The SDCA (San Diego Chinese Association) Achievement Award, 2002
Guest Professor of Shanghai Institute of Organic Chemistry
Guest Professor of Dalian Institute of Chemical Physics
Guest Professor of Wuhan University
2008年, 苏州工业园区第二届科技领军人才
2008年, "江苏省高层次创新创业人才引进计划"引进人才;
2009年, 姑苏创新创业领军人才;
2011年, 获2010年度"中国经济十大创新人物"。